Abstract: Holant problems are intimately connected with quantum theory as tensor networks. We first use techniques from Holant theory to derive new and improved results for quantum entanglement theory. We discover two particular entangled states |Ψ₆⟩ of 6 qubits and |Ψ₈⟩ of 8 qubits respectively, that have extraordinary closure properties in terms of the Bell property. Then we use entanglement properties of constraint functions to derive a new complexity dichotomy for all real-valued Holant problems containing a signature of odd arity. The signatures need not be symmetric, and no auxiliary signatures are assumed.